Spectrophotometric determination of zirconium in geological materials with Xylenol Orange.
نویسندگان
چکیده
منابع مشابه
Solid Phase Spectrophotometric Determination Of Cobalt By Xylenol Orange
A simple and sensitive solid phase spectrophotometric method for the determination of cobalt is proposed based on the reaction between cobalt and xylenol orange (XO). The reaction product is fixed on the anionic exchanger resin sephadex QAE A-25 at pH= 5. The optical absorbance of the anionic gel like resin, packed in a 1.00 mm cell is directly measured at 588.0 nm. The linear range of calibrat...
متن کاملSimultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares
A partial least squares (PLS) calibration model was developed for the simultaneous spectrophotometricdetermination of Pb (ΙΙ), Cu (ΙΙ) and Ni (ΙΙ) using xylenol orange as a chromogenic reagent. The parameterscontrolling behavior of the system were investigated and optimum conditions were selected. The calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...
متن کاملSpectrophotometric Determination of Zirconium Using Chrome Azurol
A sensitive and reproducible method for the direct spectrophotometric determination of zirconium is reported. The method is based on zirconium forms a stable bluish violet colour complex with Chrome Azurol S (CAS) which has maximum absorption at 598 nm at pH 4.2. The complex obeys Beer’s law in the concentration range of 1-7 μg/mL. Detection limit, molar absorptivity and Sandell’s sensitivity w...
متن کاملsimultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares
a partial least squares (pls) calibration model was developed for the simultaneous spectrophotometricdetermination of pb (ιι), cu (ιι) and ni (ιι) using xylenol orange as a chromogenic reagent. the parameterscontrolling behavior of the system were investigated and optimum conditions were selected. the calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...
متن کاملmultiwavelength pectrophotometric determination of stability constants of 4-(2– thiazolylazo) resorcinol (tar) with la3+, y3+ and th4+ in organic-water mixed solvents by chemometrics method & simultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares calibration method
تشکیل کمپلکس های tarبا یون های لانتانیم, ایتریم و توریم در دمای 25 درجه، قدرت یونی ثابت 0.1 مولار و در ph ثابت در مخلوط حلال های اتانول – آب و استونیتریل – آب با استفاده از روش های اسپکتروفوتومتری مورد بحث و بررسی قرار گرفت. داده های اسپکتروفوتومتری با استفاده از نرم افزار squad پردازش شدند تا ثابت های تشکیل کمپلکس اندیکاتور – فلز را محاسبه کند. نتایج نشان می دهد که درصد حلال آلی در مخلوط حلال ...
15 صفحه اولذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1988
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.37.12_671